One Step Closer to Lithium Metal Batteries that Function with Minimal External Pressure
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A team of battery researchers led by the University of California San Diego and University of Chicago has developed a new methodology to produce the potentially game-changing thin-film solid-state electrolyte called lithium phosphorus oxynitride (LiPON). The team went on to implement their free-standing version of LiPON film in functional battery tests and found that it promotes a uniformly dense lithium metal electrochemical deposition under zero external pressure, with the aid of internal compressive stress and a gold seeding layer. This work, performed by a team of battery researchers led by the University of California San Diego and University of Chicago, was published in the journal Nature Nanotechnology on August 03, 2023.
The research team is led by battery researcher and professor Ying Shirley Meng, who is affiliated with both the University of Chicago and UC San Diego. The first author is Diyi Cheng, a recently graduated Ph.D. in the Materials Science and Engineering Program at the UC San Diego Jacobs School of Engineering who is continuing his research efforts at Lawrence Berkeley National Laboratory. The team also includes researchers from Lawrence Livermore National Laboratory and UC Berkeley.
LiPON is a thin-film solid-state electrolyte that conducts lithium ions and shows strong promise for pairing with a broad range of electrode materials for the lithium battery industry of the future. However, existing methods for producing LiPON have prevented researchers from fully understanding the material. Now, the team found a way to produce this promising solid-state electrolyte in a free-standing form that allows LiPON to be studied more comprehensively. The new approach to making LiPON has also opened the door to using this solid-state electrolyte to enable lithium metal solid-state batteries that could work under minimal external pressure.
The LiPON Challenge
LiPON was originally developed by a group of scientists at Oak Ridge National Laboratory in 1992. Despite continuous research efforts over the last three decades, there remains a substantial lack of thorough understanding of LiPON’s intrinsic properties and its associated interfaces, holding back the promise and advancement of LiPON materials. Several factors leading to this dilemma include:
- LiPON is an amorphous material that gives little structural information by regular diffraction-based techniques.
- LiPON is sensitive to ambient air and electron beams, which further confines the available tools for study.
- Traditional LiPON synthesis is conducted on solid substrates. This approach is inadequate for generating conclusive signals for spectroscopic measurements.
Photograph of the new transparent, thin-film FS-LiPON material which promotes a uniformly dense lithium metal electrochemical deposition under zero external pressure, with the aid of internal compressive stress and a gold seeding layer. The team also reports that this new stand-alone thin-film version of LiPON enables fundamental research (ss-NMR and Cryo-EM) of ion conduction and electrochemical performance. Image credit: UC San Diego Laboratory for Energy Storage and Conversion / Diyi Cheng
New approach to LiPON production leads to new insights
Given the known challenges to studying LiPON, the team developed a new methodology for producing LiPON film in a free-standing form. The result is a flexible and transparent free-standing LiPON (FS-LiPON) film that is compatible with a broad range of spectroscopic techniques that have greater chances of unraveling the unique properties of LiPON over the diffraction-based techniques. This advance yielded fresh insights, described in the new Nature Nanotechnology paper on LiPON’s interfacial chemistry, thermal properties and mechanical properties. Insights include:
- Solid-state nuclear magnetic resonance measurement uncoverd a quantitative view of interface formation between lithium metal and LiPON
- Differential scanning calorimetry measurements showed a well-defined glass-transition temperature of LiPON around 207 degrees Celsius
- Nanoindentation measurement gave a Young’s modulus of LiPON around 33 GPa
Uniformly dense lithium metal deposition under zero external pressure
In addition to gleaning new fundamental insights on LiPON, the research team also implemented the new free-standing version of the solid-state electrolyte in functional battery tests. The team reports that the thin-film FS-LiPON promotes a uniformly dense lithium metal electrochemical deposition under zero external pressure, with the aid of internal compressive stress and a gold seeding layer. This finding gives valuable hints regarding interface engineering in bulk solid-state batteries.
LiPON-based thin film batteries have shown great potential for wearables and other compact electronic devices with a gigantic market. The FS-LiPON film produced in this work described by Diyi Cheng et al. in Nature Nanotechnology enabled in-depth discussions on interfacial chemistry, ion diffusion and interface engineering, which shed light on both the fundamentals and applications of LiPON materials, and could benefit the lithium solid-state battery development in many ways.
Paper
“A free-standing lithium phosphorus oxynitride thin film electrolyte promotes uniformly dense lithium metal deposition with no external pressure,” in Nature Nanotechnology on 03 August 2023.
Authors
Diyi Cheng: University of California San Diego, Thomas Wynn: University of California San Diego, Bingyu Lu: University of California San Diego, Maxwell Marple: Lawrence Livermore National Laboratory, Bing Han: University of California San Diego, Ryosuke Shimizu: University of California San Diego, Bhagath Sreenarayanan: University of California San Diego, Jeffery Bickel: University of California Berkeley, Peter Hosemann: University of California Berkeley, Yangyuchen Yang: University of California San Diego, Han Nguyen: University of California San Diego, Weikang Li: University of California San Diego, Guomin Zhu: University of California San Diego, Minghao Zhang: University of California San Diego, Ying Shirley Meng: University of Chicago and University of California San Diego
Corresponding authors
Minghao Zhang in the Department of NanoEngineering at the UC San Diego Jacobs School of Engineering: Ying Shirley Meng in the Pritzker School of Molecular Engineering at the University of Chicago, and at the UC San Diego Jacobs School of Engineering.
Funders
US Department of Energy (DOE)
National Science Foundation (NSF)
Conflict of Interest
The authors declare no competing interests.
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